To create a unique constraint
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- In Object Explorer, right-click the table to which you want to add a unique constraint, and click Design (Modify in SP1 or earlier).The table opens in Table Designer.
- From the Table Designer menu, click Indexes/Keys.
- In the Indexes/Keys dialog box, click Add.
- In the grid, click Type and choose Unique Key from the drop-down list box to the right of the property.
From https://msdn.microsoft.com/en-us/library/ms190024(v=sql.90).aspx